Material Selection and Characterization Based on Shape, Size Enhance Thermal Stability for Energy Storage Applications
DOI:
https://doi.org/10.54392/irjmt2516Keywords:
Zeta potential, Phase change materials, FTIR, Solidification, Nanoparticles, Ethelyne glycolAbstract
The study explores phase change materials enhanced with complex dispersants, primarily aimed at improving the efficiency of TES systems. The energy storage and chemical stability of transition particles are anticipated to be highly dependent on their shape and size. The samples are characterized based on melting and solidification phases evaluated. Commercial phase change materials (0.1 wt.%) such as Al2O3, C13H11NO, C6H14O6, C6H6O2, Fe2O3, KSCN, C7H6O3, and ZnO at different pH stability (2.4-7.035) having purity 99% were dispersed in H2O and Ethylene glycol. The effect of particles in phase change materials was analyzed using TGA, FTIR, XRD, zeta potential, particle size, and FESEM for Al₂O₃ and C₆H₆O₂. The TGA enhances thermal stability with melting point temperature range from 184°C to 189.90°C mixture of Al₂O₃ and C₆H₆O₂ under weight loss conditions. The performance of zeta potential and particle size was evaluated and significantly impact their pH stability of low to medium temperature. Zeta potential is measured using methods such as concentration-based volume fraction analysis and the electrophoretic migration technique. To enhance performance the synthesis and characterization of functional materials rely significantly on determining their isoelectric point. To define functional group base hydrophobic and hydrogen bonding as their primary driving forces. For PCMs, the XRD method is utilized to analyze the atomic spacing and crystal structure in order to identify every potential plane. The spherical structure of nanophase changes particles and the required form of a rod were potential improvements for high-energy storage stability applications.
References
S.P. Sukhatme, S.P. Sukhatme, (1996) Solar energy: principles of thermal collection and storage. Tata McGraw-Hill, New Delhi,
A.S. Fleischer, (2015) Thermal energy storage using phase change materials: fundamentals and applications. Springer International Publishing.
B. Zalba, J.M. Marı́n, L.F. Cabeza, H. Mehling, Review on thermal energy storage with phase change: materials, heat transfer analysis and applications. Applied thermal engineering, 23(3), (2003) 251-283. https://doi.org/10.1016/S1359-4311(02)00192-8
M.M. Kenisarin, High-temperature phase change materials for thermal energy storage. Renewable and sustainable energy reviews, 14(3), (2010) 955-970. https://doi.org/10.1016/j.rser.2009.11.011
M.M. Farid, A.M. Khudhair, S.A.K. Razack, S. Al-Hallaj, A Review on Phase Change Energy Storage: Materials and Applications. Energy Conversion and Management, 45(9-10), (2021) 4-23. https://doi.org/10.1016/j.enconman.2003.09.015
R. Elarem, T. Alqahtani, S. Mellouli, F. Askri, A. Edacherian, T. Vineet, I.A. Badruddin, J. Abdelmajid, A comprehensive review of heat transfer intensification methods for latent heat storage units. Energy Storage, 3(1), (2021) e127. https://doi.org/10.1002/est2.127
B. Patil, N. Salunke, V. Diware, A.R.S. Raheman. K.B. Ansari, Stability assessment of emerging phase change materials for solar thermal storage in absorption refrigeration: A review. International Journal of Green Energy, 22, (2025) 1-28. https://doi.org/10.1080/15435075.2024.2413678
S. Shaikh, K. Lafdi, K. Hallinan, Carbon nanoadditives to enhance latent energy storage of phase change materials. Journal of applied physics, 103(9), (2008) 094302. https://doi.org/10.1063/1.2903538
J. Wang, H. Xie, Z. Xin, Thermal properties of paraffin based composites containing multi-walled carbon nanotubes. Thermochimica Acta, 488(1-2), (2009) 39-42. https://doi.org/10.1016/j.tca.2009.01.022
T.P. Teng, B.G. Lin, Y.Y. Yeh, Characterization of heat storage by nanocomposite-enhanced phase change materials. Advanced Materials Research, 287, (2011)1448-1455. https://doi.org/10.4028/www.scientific.net/AMR.287-290.1448
C.J. Ho, J.Y. Gao, Preparation and thermophysical properties of nanoparticle-in-paraffin emulsion as phase change material. International Communications in Heat and Mass Transfer, 36(5), (2009) 467-470. https://doi.org/10.1016/j.icheatmasstransfer.2009.01.015
A.V. Arasu, A.S. Mujumdar, Numerical study on melting of paraffin wax with Al2O3 in a square enclosure. International Communications in Heat and Mass Transfer, 39(1), (2012) 8-16. https://doi.org/10.1016/j.icheatmasstransfer.2011.09.013
A. Sarı, A. Karaipekli, Thermal conductivity and latent heat thermal energy storage characteristics of paraffin/expanded graphite composite as phase change material. Applied thermal engineering, 27(8-9), (2007) 1271-1277. https://doi.org/10.1016/j.applthermaleng.2006.11.004
A. Gil, E. Oró, L. Miró, G. Peiró, Á. Ruiz, J.M. Salmerón, L.F. Cabeza, Experimental analysis of hydroquinone used as phase change material (PCM) to be applied in solar cooling refrigeration. International journal of refrigeration, 39, (2014) 95-103. https://doi.org/10.1016/j.ijrefrig.2013.05.013
A.T. Muzhanje, M.A. Hassan, A.A. El-Moneim, H. Hassan, Preparation and physical and thermal characterizations of enhanced phase change materials with nanoparticles for energy storage applications. Journal of Molecular Liquids, 390, (2023) 122958. https://doi.org/10.1016/j.molliq.2023.122958
X. Liu, P. Mäki-Arvela, A. Aho, Z. Vajglova, V.M. Gun’ko, I. Heinmaa, N. Kumar, K. Eränen, T. Salmi, D.Y. Murzin, Zeta potential of beta zeolites: Influence of structure, acidity, pH, temperature and concentration. Molecules, 23(4), (2018) 946. https://doi.org/10.3390/molecules23040946
B.Y. Patil, N.P. Salunke, V.R. Diware, V.K. Suryavanshi, P.S. Patil, Concentration of nano fluid/base fluid suspension enhance surface charge with pH stability for low to medium temperature phase change materials. ShodhKosh: Journal of Visual and Performing Arts, 5(4), (2024) 525–542. https://doi.org/10.29121/shodhkosh.v5.i4.2024.2258
J.T. Miller, M. Schreier, A.J. Kropf, J.R. Regalbuto, A fundamental study of platinum tetraammine impregnation of silica: 2. The effect of method of preparation, loading, and calcination temperature on (reduced) particle size. Journal of Catalysis, 225(1), (2004) 203-212. https://doi.org/10.1016/j.jcat.2004.04.007
P. Mäki-Arvela, D.Y. Murzin, Effect of catalyst synthesis parameters on the metal particle size. Applied Catalysis A: General, 451, (2013) 251-281. https://doi.org/10.1016/j.apcata.2012.10.012
K. Rodríguez, M. Araujo, Temperature and pressure effects on zeta potential values of reservoir minerals. Journal of colloid and interface science, 300(2), (2006) 788-794. https://doi.org/10.1016/j.jcis.2006.04.030
S. Chakraborty, P.K. Panigrahi, Stability of nanofluid: A review. Applied Thermal Engineering, 174, (2020) 115259. https://doi.org/10.1016/j.applthermaleng.2020.115259
N. Hordy, D. Rabilloud, J.L. Meunier, S. Coulombe, High temperature and long-term stability of carbon nanotube nanofluids for direct absorption solar thermal collectors. Solar Energy, 105, (2014) 82-90. https://doi.org/10.1016/j.solener.2014.03.013
D. Yılmaz Aydın, M. Gürü, Nanofluids: preparation, stability, properties, and thermal performance in terms of thermo-hydraulic, thermodynamics and thermo-economic analysis. Journal of Thermal Analysis and Calorimetry, (2021)1-34. https://doi.org/10.1007/s10973-021-11092-8
K. Cacua, F. Ordoñez, C. Zapata, B. Herrera, E. Pabón, R. Buitrago-Sierra, Surfactant concentration and pH effects on the zeta potential values of alumina nanofluids to inspect stability. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 583, (2019) 123960. https://doi.org/10.1016/j.colsurfa.2019.123960
S. Bhattacharjee, DLS and zeta potential–what they are and what they are not?. Journal of controlled release, 235, (2016) 337-351. https://doi.org/10.1016/j.jconrel.2016.06.017
S.K. Sharma, S.M. Gupta, Preparation and evaluation of stable nanofluids for heat transfer application: a review. Experimental Thermal and Fluid Science, 79, (2016) 202-212. https://doi.org/10.1016/j.expthermflusci.2016.06.029
H.W. Chiam, W.H. Azmi, N.A. Usri, Rizalman Mamat, N.M. Adam, Thermal conductivity and viscosity of Al2O3 nanofluids for different based ratio of water and ethylene glycol mixture. Experimental Thermal and Fluid Science, 81, (2017) 420-429. https://doi.org/10.1016/j.expthermflusci.2016.09.013
V. Brancato, A. Frazzica, A. Sapienza, A. Freni, Identification and characterization of promising phase change materials for solar cooling applications. Solar Energy Materials and Solar Cells. 160, (2017) 225-232. https://doi.org/10.1016/j.solmat.2016.10.026
A. Gil, E. Oró, G. Peiró, S. Álvarez, L.F. Cabeza, Material selection and testing for thermal energy storage in solar cooling. Renewable Energy, 57, (2013) 366-371. https://doi.org/10.1016/j.renene.2013.02.008
M.M.A. Khan, R. Saidur, F.A. Al-Sulaiman, A review for phase change materials (PCMs) in solar absorption refrigeration systems. Renewable and sustainable energy reviews. 76, (2017) 105-137. https://doi.org/10.1016/j.rser.2017.03.070
A.M. Schrand, M.F. Rahman, S.M. Hussain, J.J. Schlager, D.A. Smith, A.F. Syed, Metal‐based nanoparticles and their toxicity assessment. Wiley interdisciplinary reviews: Nanomedicine and Nanobiotechnology, 2(5), (2010) 544-568. https://doi.org/10.1002/wnan.103
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Bhushan Y. Patil, Nilesh P. Salunke, Vijay R. Diware (Author)

This work is licensed under a Creative Commons Attribution 4.0 International License.